| Polyurethanes
or Urethanes are terms that are used interchangeably
for a family of elastomers that were invented as ‘artificial
rubbers’ during World War II. Polyurethane elastomers
are a unique breed of Engineering materials that combine the
advantages of rigid plastics, metals and ceramics with the flexibility
and elasticity of rubber. Polyurethanes
are available as Thermosets or Thermoplastics:
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Thermosets
are a blend of a resin and a curative, that yield some
high performance Engineering properties that are not obtained
by any other process. Molding process is similar to Epoxies,
bakelite, etc., wherein a Resin and a curative are blended
to form a chemical cross linking, and once this reaction
takes place, the mix has to be poured into a mold cavity
before it cures. Once it is cured it cannot be re-melted
or re-ground and re-used. Main advantages of this molding
process is the ability to mold large or complex shaped
parts with fairly in-expensive molds, and the ability
to obtain a variety of physical properties and combination
of properties that can be optimized for a given application.
These are commonly known as Cast Polyurethanes.
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Thermoplastic polyurethanes
are available in pellet shapes, similar to other plastic
materials and can be re-melted and molded by injection
molding or extrusion. The size of the molded part or the
cross section of the extrusion is limited. |
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Cast
Polyurethanes:
Cast Polyurethanes are a versatile family of elastomers that
can be molded to optimize a combination of the following properties,
depending on the application:
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Excellent Resilience (high or low )
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Extra Toughness and Durability
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Very high load bearing capacity
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High Tear Strength and Cut Resistance
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Low Compression Set
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Very good impact resistance
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Outstanding Abrasion resistance
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Good machinability
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Oil, solvent, water and ozone resistance.
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Non-marking
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Mold, mildew , fungus resistance
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Flex fatigue resistance
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Good Electrical properties
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Friction (high or low)
Mechanical
Properties:
Cast Polyurethanes have an extraordinary combination of many
of the above properties in the same material, unlike any other
engineering material. The molder has the ability to vary the
ratio between the resin and the curative to optimize some
of these properties ( and some times it may be at the cost
of some other properties ). So, a properly engineered compound
can outlast an identical hardness part by a factor of several
times.
Types
of Polyurethanes:
Cast Polyurethanes based on TDI, MDI,PPDI, polyethers, polyesters
and polycaprolactones as building blocks, offer a wide variety
of application possibilities and advantages.
Polyethers perform well
in dynamic applications and in hydrolytic environments. They
are extensively used in applications such as die-forming pads,
press brake dies, die springs, fork lift tires, roller coaster
wheels, rolls for steel and paper mills.
Polyesters have superior
cut, tear and abrasion resistance as well as better resistance
to oil and solvents. Typical applications include hydraulic
seals, scraper blades, rolls for graphic arts, pipeline pigs,
chute liners, etc.
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